B(C6F5)3 as a C6F5 transfer reagent in zirconium chemistry:: facile formation of the borole-bridged triple-decker complex [Zr2Cp"2(C6F5)2{μ-η5:η5-C4H4BCH2-η3,κF-CHCHCHB(C6F5)3}]

被引：24

作者：

Woodman, TJ

Thornton-Pett, M

Bochmann, M ^{[1
]}

机构：

[1] Univ E Anglia, Sch Chem Sci, Norwich NR4 7TJ, Norfolk, England

[2] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 04期

关键词：

D O I：

10.1039/b009016f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Warming mixtures of (Cp-R)Zr(eta (3)-C4H7)(eta (4)-C4H6) and B(C6F5)(3) leads to complete transfer of all three C6F5 substituents of a B(C6F5)(3) molecule to give borole-bridged triple-decker complexes with a Zr2C4B core, a zwitterionic structure and an unusually strong Zr-F donor interaction.

引用

收藏

页码：329 / 330

页数：2

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