Organometallic chemistry inside the pore walls of mesostructured silica materials

被引：56

作者：

Dufaud, V

Beauchesne, F

Bonneviot, L

机构：

[1] Ecole Normale Super Lyon, Chim Lab, CNRS ENS, UMR 5182, F-69364 Lyon, France

[2] Inst Rech Catalyse, F-69626 Villeurbanne, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 22期

关键词：

heterogeneous catalysis; hydrogenation; mesoporous materials; rhodium; silicates;

D O I：

10.1002/anie.200500454

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Covalently imprisoned within pore walls of mesostructured porous silica, organophosphanyl transition-metal complexes (Z, see picture) are still able to effect heterogeneous hydrogenation catalysis. The key to the synthetic protocol that leads to the well-defined metal sites lies in silylation of the material prior to extraction of the surfactant template. TEOS = tetraethylorthosilicate. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：3475 / 3477

页数：3

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