Morphotropic phase boundary in solid solution systems of perovskite-type oxide ferroelectrics

被引:173
作者
Ishibashi, Y [1 ]
Iwata, M [1 ]
机构
[1] Nagoya Univ, Sch Engn, Dept Appl Phys, Nagoya, Aichi 4648603, Japan
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS | 1998年 / 37卷 / 8B期
关键词
morphotropic phase boundary; dielectric susceptibility; free energy; Landau theory;
D O I
10.1143/JJAP.37.L985
中图分类号
O59 [应用物理学];
学科分类号
摘要
The origin of the appearance of the morphotropic phase boundary in the perovskite-type oxide solid solution systems and the increase in the dielectric susceptibilities in the vicinity of the boundary is theoretically clarified on the basis of a Landau-type free energy function. The dielectric susceptibilities are concretely expressed in terms of the model parameters, and found to diverge at the morphotropic phase boundary within the present model.
引用
收藏
页码:L985 / L987
页数:3
相关论文
共 6 条
[1]  
DEVONSHIRE AF, 1951, PHILOS MAG, V42, P1065
[2]  
DEVONSHIRE AF, 1949, PHILOS MAG, V40, P1040
[3]   Phase diagrams in successive phase transitions in ferroelectrics with perovskite-type structure: Cases of the first order transitions from the cubic phase [J].
Fujita, K ;
Ishibashi, Y .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 1997, 36 (08) :5214-5218
[4]   Roles of the higher order anisotropic terms in successive structural phase transitions: The method of determination of phenomenological parameters [J].
Fujita, K ;
Ishibashi, Y .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1997, 36 (1A) :254-259
[5]  
HUAN MJ, 1989, FERROELECTRICS, V99, P63
[6]  
Jaffe B., 1971, PIEZOELECTRIC CERAMI