The role of acrolein in the inhibition of the acid corrosion of iron with propargyl alcohol

被引：12

作者：

Avdeev, YG

Podobaev, NI

机构：

[1] Kaluga State Pedagog Univ, Kaluga 248023, Russia

[2] Moscow State Pedag Univ, Moscow 119882, Russia

来源：

PROTECTION OF METALS | 2005年 / 41卷 / 06期

关键词：

Iron; Alcohol; Inorganic Chemistry; Protective Effect; Sulfuric Acid;

D O I：

10.1007/s11124-005-0086-0

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

Potentiodynamic polarization was used to investigate the effect of acrolein (formed from propargyl alcohol via acid-induced isomerization) on the electrode processes at Armco iron in hydrochloric and sulfuric acid solutions. In solutions of mineral acids, acrolein is ineffective and inferior to propargyl alcohol in the inhibition of iron corrosion. It was found that acrolein can be cathodically reduced during the corrosion process, whereas the isomerization of propargyl alcohol into acrolein should reduce the protective effect of the inhibitor.

引用

页码：592 / 596

页数：5

共 22 条

[1] Surface-enhanced Raman scattering spectroscopy studies on the inhibition mechanism of propargyl alcohol for iron corrosion in hydrochloric acid [J].

Aramaki, K ;

Fujioka, E .

CORROSION, 1996, 52 (02) :83-91

[2]

Barton D., 1979, COMPREHENSIVE ORGANI, V1

[3]

FAVORSKAYA T, 1939, J GEN CHEM USSR, V9, P386

[4]

FRENIER WW, 1988, P INT C CORR 88 ST L

[5]

KLYBA NS, 2003, THESIS IRKUTSK

[6]

KUCHEROV VF, 1973, KHIMIYA ATSETILENOVY, P99

[7]

Patai S., 1964, The chemistry of alkenes, DOI DOI 10.1002/9780470771044

[8]

PETROVA LA, 1966, THESIS MOSK

[9]

Podobaev N.I., 1969, ZH PRIKL KHIM, V42, P1569

[10]

Podobaev N I, 2001, ZASHCH MET, V37, P170

← 1 2 3 →