Relaxation of silver ions in fast ion conducting molybdate glasses

被引：25

作者：

Bhattacharya, S ^{[1
]}

Ghosh, A ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Solid State Phys, Kolkata 700032, W Bengal, India

来源：

SOLID STATE IONICS | 2005年 / 176卷 / 13-14期

关键词：

fast ion conducting glass; Ag1; conductivity relaxation;

D O I：

10.1016/j.ssi.2005.03.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The conductivity relaxation in the frequency range from 10 Hz to 2 MHz and in the temperature range from 108 to 303 K for the fast ion conducting AgI-Ag2O-MoO3 glasses has been reported. It has been observed that the conductivity relaxation in these glasses is highly nonexponential and that the conductivity relaxation mechanism is independent of temperature but is dependent on composition. It has been further observed that the motion of Ag+ ions is decoupled more and more from the viscous motion of the glassy matrix with the increase of AgI content in the composition, giving rise to the increase of the conductivity. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1243 / 1247

页数：5

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