N-heterocyclic carbene ligands as cyanide mimics in diiron models of the all-iron hydrogenase active site

被引：156

作者：

Capon, JF ^{[1
]}

El Hassnaoui, S ^{[1
]}

Gloaguen, F ^{[1
]}

Schollhammer, P ^{[1
]}

Talarmin, J ^{[1
]}

机构：

[1] Univ Bretagne Occidentale, Fac Sci, UMR CNRS 6521, F-29238 Brest, France

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 09期

关键词：

D O I：

10.1021/om049132h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction Of [Fe-2(mu-S(CH2)(3)S)(CO)(6)] with an excess of 1,3-dimethylimidazol-2-ylidene (L-Me) affords the mono- and disubstituted species [Fe-2(mu-S(CH2)(3)S)-(CO)(5)(L-Me)] (1) and [Fe-2(Al-S(CH2)(3)S)(CO)(4)(L-Me)(2)] (2), respectively. The structures of 1 and 2 have been determined by X-ray crystallography.

引用

页码：2020 / 2022

页数：3

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