An N-heterocyclic carbene as a bidentate hemilabile ligand:: a synchrotron X-ray diffraction and density functional theory study

被引：41

作者：

Dioumaev, VK

Szalda, DJ

Hanson, J

Franz, JA

Bullock, RM ^{[1
]}

机构：

[1] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

[2] Pacific NW Natl Lab, Richland, WA 99352 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 14期

关键词：

D O I：

10.1039/b303762b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The N-heterocyclic carbene ligand IMes was shown by synchrotron crystallography and DFT computations to adopt a hemilabile bidentate coordination mode in CpM(CO)(2)(IMes)+B(C6F5)(4)(-) (M = Mo, W), with a C=C bond of one mesityl weakly coordinated to the metal.

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页码：1670 / 1671

页数：2

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