New stable catalysts of the Pauson-Khand annelation

被引:34
作者
Comely, AC
Gibson, SE
Stevenazzi, A
Hales, NJ
机构
[1] Kings Coll London, Dept Chem, London WC2R 2LS, England
[2] AstraZeneca UK Ltd, Macclesfield SK10 4TG, Cheshire, England
关键词
D O I
10.1016/S0040-4039(00)02204-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A range of phosphine- and phosphite-substituted carbonylcobalt(0) complexes have been synthesised and screened as catalysts of the Pauson Khand annelation. The readily prepared stable solid, heptacarbonyl(triphenylphosphine)dicobalt(0) 1. performed well (78% yield) in a benchmark annelation reaction. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1183 / 1185
页数:3
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