Synthesis and structure of N-heterocyclic carbene complexes of uranyl dichloride

被引：85

作者：

Oldham, WJ

Oldham, SM

Scott, BL

Abney, KD

Smith, WH

Costa, DA

机构：

[1] Univ Calif Los Alamos Natl Lab, Nucl Mat & Technol Div, Los Alamos, NM 87545 USA

[2] Univ Calif Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 15期

关键词：

D O I：

10.1039/b102649f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of UO2Cl2(thf)(3) in THF with two equivalents of 1,3-dimesitylimidazole-2-ylidene (IMes) or 1,3-dimesityl-4,5-dichloroimidazole-2-ylidene (IMesCl(2)) yields novel monomeric uranyl N-heterocyclic carbene complexes, representing the first examples of actinyl carbon bonds.

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页码：1348 / 1349

页数：2

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