Metal-Organic Framework Single Crystals as Photoactive Matrices for the Generation of Metallic Microstructures

被引:94
作者
Ameloot, Rob [1 ]
Roeffaers, Maarten B. J. [2 ]
De Cremer, Gert [1 ]
Vermoortele, Frederik [1 ]
Hofkens, Johan [2 ]
Sels, Bert F. [1 ]
De Vos, Dirk E. [1 ]
机构
[1] Katholieke Univ Leuven, Dept Microbial & Mol Syst, Ctr Surface Chem & Catalysis, B-3001 Heverlee, Belgium
[2] Katholieke Univ Leuven, Dept Chem, B-3001 Heverlee, Belgium
关键词
LASER; MOF-5; PHOTOCATALYSTS; PALLADIUM;
D O I
10.1002/adma.201100063
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The photocatalytic properties of MOF-5, a highly porous metal-organic framework (MOF) material, can be exploited to generate metallic patterns by direct laser writing. The strict confinement of photoreduction to the focal volume of the laser beam, where irradiation intensity is highest, allows the generation of 3D metallic structures inside a single MOF-5 crystal.
引用
收藏
页码:1788 / +
页数:5
相关论文
共 33 条
[1]   Multiphoton laser direct writing of two-dimensional silver structures [J].
Baldacchini, T ;
Pons, AC ;
Pons, J ;
LaFratta, CN ;
Fourkas, JT ;
Sun, Y ;
Naughton, MJ .
OPTICS EXPRESS, 2005, 13 (04) :1275-1280
[2]   Electronic and vibrational properties of a MOF-5 metal-organic framework: ZnO quantum dot behaviour [J].
Bordiga, S ;
Lamberti, C ;
Ricchiardi, G ;
Regli, L ;
Bonino, F ;
Damin, A ;
Lillerud, KP ;
Bjorgen, M ;
Zecchina, A .
CHEMICAL COMMUNICATIONS, 2004, (20) :2300-2301
[3]   Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication [J].
Cumpston, BH ;
Ananthavel, SP ;
Barlow, S ;
Dyer, DL ;
Ehrlich, JE ;
Erskine, LL ;
Heikal, AA ;
Kuebler, SM ;
Lee, IYS ;
McCord-Maughon, D ;
Qin, JQ ;
Röckel, H ;
Rumi, M ;
Wu, XL ;
Marder, SR ;
Perry, JW .
NATURE, 1999, 398 (6722) :51-54
[4]   Industrial applications of metal-organic frameworks [J].
Czaja, Alexander U. ;
Trukhan, Natalia ;
Mueller, Ulrich .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1284-1293
[5]   A New Photoactive Crystalline Highly Porous Titanium(IV) Dicarboxylate [J].
Dan-Hardi, Meenakshi ;
Serre, Christian ;
Frot, Theo ;
Rozes, Laurence ;
Maurin, Guillaume ;
Sanchez, Clement ;
Ferey, Gerard .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (31) :10857-+
[6]   Photoactivation of silver-exchanged zeolite A [J].
De Cremer, Gert ;
Antoku, Yasuko ;
Roeffaers, Maarten B. J. ;
Sliwa, Michel ;
Van Noyen, Jasper ;
Smout, Steve ;
Hofkens, Johan ;
De Vos, Dirk E. ;
Sels, Bert F. ;
Vosch, Tom .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (15) :2813-2816
[7]   In Situ Observation of the Emission Characteristics of Zeolite-Hosted Silver Species During Heat Treatment [J].
De Cremer, Gert ;
Coutino-Gonzalez, Eduardo ;
Roeffaers, Maarten B. J. ;
De Vos, Dirk E. ;
Hofkens, Johan ;
Vosch, Tom ;
Sels, Bert F. .
CHEMPHYSCHEM, 2010, 11 (08) :1627-1631
[8]   Optical Encoding of Silver Zeolite Microcarriers [J].
De Cremer, Gert ;
Sels, Bert F. ;
Hotta, Jun-ichi ;
Roeffaers, Maarten B. J. ;
Bartholomeeusen, Evelyne ;
Coutino-Gonzalez, Eduardo ;
Valtchev, Valentin ;
De Vos, Dirk E. ;
Vosch, Tom ;
Hofkens, Johan .
ADVANCED MATERIALS, 2010, 22 (09) :957-+
[9]   Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks [J].
Deng, Hexiang ;
Doonan, Christian J. ;
Furukawa, Hiroyasu ;
Ferreira, Ricardo B. ;
Towne, John ;
Knobler, Carolyn B. ;
Wang, Bo ;
Yaghi, Omar M. .
SCIENCE, 2010, 327 (5967) :846-850
[10]   Isoreticular MOFs as Efficient Photocatalysts with Tunable Band Gap: An Operando FTIR Study of the Photoinduced Oxidation of Propylene [J].
Gascon, Jorge ;
Hernandez-Alonso, Maria D. ;
Almeida, Ana Rita ;
van Klink, Gerard P. M. ;
Kapteijn, Freek ;
Mul, Guido .
CHEMSUSCHEM, 2008, 1 (12) :981-983