Integration of electrochemical generator and detector of nitric oxide with the aid of the iron porphyrin

被引：11

作者：

Chi, YW ^{[1
]}

Chen, JY ^{[1
]}

Miyake, M ^{[1
]}

机构：

[1] Univ Fukui, Dept Appl Phys, Fukui 9108507, Japan

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2005年 / 7卷 / 12期

关键词：

electrochemical generator cell; amperometric detection; nitric oxide; nitrite; iron porphyrin; catalytic reaction;

D O I：

10.1016/j.elecom.2005.08.026

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

An electrochernical cell of generating nitric oxide (NO) was constructed in order to realize the catalytic reaction of nitrite by iron porphyrin [Y. Chi, J. Chen, K. Aoki, Inorg. Chem. 43 (2004) 8437]. The cell was composed of the generator of the iron porphyrin-including Nafion (R)-coated electrode, the ion-exchange membrane, and the electrochemical detector of NO. The reduction of iron porphyrin in the presence of nitrite at the generator coordinates nitrite to form the NO-included complex, of which oxidation releases NO. The water-dissolved NO diffused to the detector through the membrane to block nitrite. It was detected by voltammetry with the aid of the oxidative catalytic reaction of iron porphyrin. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1205 / 1208

页数：4

共 19 条

[1] ELECTROCATALYTIC REDUCTION OF NITRITE TO AMMONIA BASED ON A WATER-SOLUBLE IRON PORPHYRIN [J].