Unstable products from the ozonation of C60 in solvents

被引:10
作者
Heymann, D
Cataldo, F
机构
[1] Rice Univ, Houston, TX 77251 USA
[2] Progega Snc, I-00133 Rome, Italy
来源
FULLERENE SCIENCE AND TECHNOLOGY | 2001年 / 9卷 / 01期
关键词
D O I
10.1081/FST-100000166
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The ozonation of a solution of C-60 in toluene results in the formation of several unstable compounds C60X and C60Y[1-5] which decay completely at room temperature within about 1 h. The products are oxides C60O[6,6], C60O2[I], C60O2[II], and possibly an isomer of C60O3 The transformations are not due to oxidation by atmospheric oxygen but are spontaneous. The ozonation of a solution of C60O[6,6] in toluene results in the formation of two unstable compounds C(60)Z[1-2] which also decay completely to C60O2[I] and C60O2[II] It is suggested that all. unstable "parents" are ozonides.
引用
收藏
页码:71 / 76
页数:6
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