Gradient polymer layers by "grafting to" approach

被引：97

作者：

Ionov, L ^{[1
]}

Zdyrko, B

Sidorenko, A

Minko, S

Klep, V

Luzinov, I

Stamm, M

机构：

[1] Inst Polymer Res Dresden, Dresden, Germany

[2] Clemson Univ, Sch Mat Sci & Engn, Clemson, SC 29634 USA

[3] Clarkson Univ, Dept Chem, Potsdam, NY 13699 USA

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 01期

关键词：

combinatorial approach; films; grafting; polymer; surfaces;

D O I：

10.1002/marc.200300216

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new method for the preparation of ultrathin tethered polymer layers with gradually changing thickness was developed utilizing the "grafting to" approach. The grafting procedure allowed translation of the temperature gradient created in a heating stage into a gradient of polymer chain grafting density. The gradient tethered polymer layers demonstrated gradual changes in wetting properties and morphology transition from pinned micelles to a brush regime along the substrate.

引用

页码：360 / 365

页数：6

共 26 条

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[Anonymous], ANGEW CHEM

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