Oxidation of chiral 9-fluorinated substrates by castor stearoyl-ACP Δ9 desaturase yields novel products

被引：7

作者：

Behrouzian, B

Dawson, B

Buist, PH

Shanklin, J

机构：

[1] Carleton Univ, Dept Chem, Ottawa, ON K1S 5B6, Canada

[2] Brookhaven Natl Lab, Dept Biol, Upton, NY 11973 USA

[3] Hlth Canada, Div Res Serv, Hlth Prod & Food Branch, Ottawa, ON K1A 0L2, Canada

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 08期

关键词：

D O I：

10.1039/b100035g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Desaturation of (S)-9-fluorostearoyl-ACP using stearoyl-ACP Delta (9) desaturase yielded mainly (E)-9-fluoroalk-9-enic product, while desaturation of (R)-9-fluorostearoyl-ACP gave the novel (Z)-9-fluoroalk-9-ene and (Z)-9-fluoroalk-10-ene.

引用

页码：765 / 766

页数：2

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