Gels as templates for nanotubes

被引：67

作者：

Jung, JH

Shinkai, S

机构：

[1] Korea Basic Sci Inst, Nanomat Team, Taejon 305333, South Korea

[2] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8128581, Japan

来源：

TEMPLATES IN CHEMISTRY I | 2004年 / 248卷

关键词：

cholesterol; crown ether; gelator; nanotube; organogel; self-assembly; sol-gel transcription; sugar;

D O I：

10.1007/b99915

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The design of artificial models for "biomineralization"processes that utilize solgel polycondensation has led to a merging of inorganic materials science and supramolecular organic chemistry. This chapter introduces self-assembled superstructures of cyclohexane-based, sugar-integrated, and crown-appended cholesterol gelators, which are used as versatile building blocks in organogels and as templates for sol-gel transcription. This review focuses on the use of these self-assembled organic superstructures in the creation of novel inorganic materials with controlled morphologies.

引用

页码：223 / 260

页数：38

共 124 条

[1]

Abdallah DJ, 2000, ADV MATER, V12, P1237

[2]

Amaike M, 2001, CHEM LETT, P620

[3] New sugar-based gelators with an amino group, the gelation ability of which is remarkably reinforced by the hydrogen bond and the metal coordination [J].