Build-up of an Al4P6Li4 cage from an Al4N4 cubane: Synthesis and structure of [Li(OC4H8)](4)[{(AlMe)[mu-P(C6H11)]}(2){mu-P(C6H11)}](2)center dot C(6)H(5)Me

被引：22

作者：

Allan, RE ^{[1
]}

Beswick, MA ^{[1
]}

Raithby, PR ^{[1
]}

Steiner, A ^{[1
]}

Wright, DS ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 22期

关键词：

D O I：

10.1039/dt9960004153

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The acid-base reaction of the Al-III imido cubane [AlMe(Nmes)](4) (mes = 2,4,6-Me(3)C(6)H(2)) with Li[PH(C6H11)] yielded the heterobimetallic cage complex [Li(OC4H8)](4)- [{(AlMe)[mu-P(C6H11)]}(2){mu-P(C6H11)}](2) . C(6)H(5)Me, the metallacyclic tetraanion of which is the first example of an. Al-III phosphinidine anion.

引用

页码：4153 / 4154

页数：2

共 35 条

[1]

ALLAN RE, 1996, J CHEM SOC CHEM COMM, P1501

[2] COMPLEXES OF ORGANOALUMINUM COMPOUNDS .10. CRYSTAL AND MOLECULAR-STRUCTURES OF THE CAGE COMPOUNDS BIS-MU-METHYLAMIDO-HEXA-MU-3-METHYLIMIDO-BIS(DIMETHYLALUMINIUM)-HEXAKIS(METHYLALUMINIUM) AND BIS-MU-METHYLAMIDO-HEXA-MU-3-METHYLIMIDO-BIS(DIMETHYLGALLIUM)-HEXAKIS-(METHYLGALLIUM) [J].