Selective C-H bond activation by a supramolecular host-guest assembly

被引：160

作者：

Leung, DH ^{[1
]}

Fiedler, D ^{[1
]}

Bergman, RG ^{[1
]}

Raymond, KN ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 08期

关键词：

C-H activation; diastereoselectivity; gallium; host-guest systems; iridium; supramolecular chemistry;

D O I：

10.1002/anie.200352772

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Interior design: A chiral supramolecular tetrahedral [Ga4L 6]12- host (L=bis(bidentate) ligand) is shown to encapsulate a half-sandwich iridium complex. This host-guest assembly reacts with aldehydes through C-H bond activation, which occurs within the host interior. This activation occurs with high size and shape specificity as well as modest diastereoselectivity (d.r. 55:45-70:30) owing to the well-defined shape of the host cavity.

引用

页码：963 / 966

页数：4

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