Microwave effects in the synthesis of polyethers by phase transfer catalysis

被引:36
作者
Hurduc, N
Abdelylah, D
Buisine, JM
Decock, P
Surpateanu, G
机构
[1] LAB DYNAM & STRUCT MATERIAUX MOL,URA CNRS 801,F-59379 DUNKERQUE,FRANCE
[2] UNIV LITTORAL,LAB DYNAM & STRUCT MATERIAUX MOL,URA CNRS 801,F-59379 DUNKERQUE,FRANCE
[3] UNIV LITTORAL,EQUIPE THERMOPHYS MATIERE CONDENSEE,LAB ANAL & CHIM HYPERFREQUENCES,F-59379 DUNKERQUE,FRANCE
关键词
D O I
10.1016/S0014-3057(96)00069-9
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Phase transfer catalysis processes with or without microwave fields are studied. A polycondensation reaction was used as a model, starting from 3,3-bis(chloromethyl)oxetane and various bisphenols. The results obtained show the advantages of microwave fields, concerning the molecular weights for crystalline polymers and the reaction time for all types of structures. (C) 1997 Elsevier Science Ltd. All rights reserved.
引用
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页码:187 / 190
页数:4
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