NaCl adsorption in multi-walled carbon nanotube/active carbon combination electrode

被引:49
作者
Dai, K
Shi, LY
Zhang, DS
Fang, JH
机构
[1] Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200444, Peoples R China
[2] Shanghai Univ, Coll Sci, Shanghai 200444, Peoples R China
[3] Shanghai Univ, Nanosci & Technol Ctr, Shanghai 200444, Peoples R China
关键词
carbon nanotube; active carbon; salt water; desalination;
D O I
10.1016/j.ces.2005.07.030
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this paper, we proposed a new process for fabricating electrochemical double layer capacitors employing active carbon and multiwalled carbon nanotubes to adsorb Na+ and Cl- from NaCl solution. Due to their unique mesoporosity, active carbons have high ability to desalt NaCl solution. But they have many defects such as high electrical resistance, high-energy consumption and low intensity. Since carbon nanotube is a new material which has high intensity and low resistance, we can composite the merits of active carbon and carbon nanotube and develop carbon nanotube/active carbon materials combination electrode. It was tested that when carbon nanotube content in carbon materials is 10%, the characteristics of combination electrode is the best for us to desalt brackish water because of their high desalination characterization and low energy consumption. Though there are a few technical problems to be solved, our results show a promising technique for desalting salt water. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:428 / 433
页数:6
相关论文
共 17 条
[1]   Diagnostic analyses for mechanisms of self-discharge of electrochemical capacitors and batteries [J].
Conway, BE ;
Pell, WG ;
Liu, TC .
JOURNAL OF POWER SOURCES, 1997, 65 (1-2) :53-59
[2]  
Ghenciu AF, 2002, CURR OPIN SOLID ST M, V6, P389, DOI 10.1016/S1359-0286(02)00108-0
[3]  
HAICHAO L, 2004, ELECTROCHIMA ACTA, V49, P3463
[4]   Multi-step purification of carbon nanotubes [J].
Hou, PX ;
Bai, S ;
Yang, QH ;
Liu, C ;
Cheng, HM .
CARBON, 2002, 40 (01) :81-85
[5]   Preparation of high-surface-area activated carbons from coconut shell [J].
Hu, ZH ;
Srinivasan, MP .
MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 27 (01) :11-18
[6]   Identifying nano SnS as a new electrode material for electrochemical capacitors in aqueous solutions [J].
Jayalakshmi, M ;
Rao, MM ;
Choudary, BM .
ELECTROCHEMISTRY COMMUNICATIONS, 2004, 6 (11) :1119-1122
[7]   High voltage electrochemical double layer capacitors using conductive carbons as additives [J].
Michael, MS ;
Prabaharan, SRS .
JOURNAL OF POWER SOURCES, 2004, 136 (02) :250-256
[8]  
MOTOO T, 1997, J POWER SOURCES, V66, P186
[9]  
NISHINO A, 1988, TANSO, V132, P57
[10]  
PAULO L, 2004, J COLLOID INTERF SCI, V280, P149