Dynamics of the simplest reaction of a carbon atom in a tetrahedral environment

被引：39

作者：

Camden, JP ^{[1
]}

Bechtel, HA ^{[1
]}

Zare, RN ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 42期

关键词：

gas-phase chemistry; hot-atom chemistry; methane; reaction dynamics;

D O I：

10.1002/anie.200352642

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The abstraction reaction H + CD4→CD3 + HD is studied at a collision energy of ∼2 eV under single-collision conditions (see picture). Most of the available energy appears in product translational motion, and the CD3 product is scattered sideways and backward with respect to the incident H-atom direction. This behavior is unexpected based on simple atom-diatom models.

引用

页码：5227 / 5230

页数：4

共 29 条

[1] Quantum scattering calculations on chemical reactions [J].