Volatile heavy metal mobility in silicate liquids: Implications for volcanic degassing and eruption prediction

The volatilization of Cd, Re, Tl, Pb, Sb and Te from melts in the system CaO-MgO-Al2O3-SiO2 (CMAS) and Na2O-MgO-Al2O3-SiO2 (NMAS) has been investigated at 0.1 MPa and 1200-1350 degrees C. Experiments were conducted in air using metal-doped melts in Pt crucibles. Analysis of quenched glasses by Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) normal to the melt/gas interface produced concentration profiles for Cd, Re, Tl, Pb, Sb and Te to which a semi-infinite one-dimensional diffusion model could be applied to extract diffusion coefficients (D). The melt was also doped with Cu, Zn, In, Mo, Sn and W but concentration profiles for these metals did not develop. In the CMAS composition at 1300 degrees C, the fastest diffusing element was Cd having a logD(Cd)=-6.5 +/- 0.2. The slowest element was Re with logD(Re)=-7.5 +/- 0.3. Diffusivities of Sb, Te, Pb and Tl have intermediate values where logD(Sb)=-7.1 +/- 0.1, logD(Te)=-7.2 +/- 0.3, logD(Pb)=-7.1 0.2, logD(Ti)=-7.0 +/- 0.2 cm(2)/S. In the WAS composition, logD(Re)=-6.5 +/- 0.2, logD(Sb)=-6.0 +/- 0.2, logD(Pb)= -6.1 +/- 0.1, logD(Tl)=-5.8 +/- 0.2 cm(2)/S (values for Cd and Te were not determined). Differences in diffusivity of volatile heavy metal ions to a melt-gas interface lead to significant fractionation between these metals in magmas during degassing. Given the observed differences in Cd and Re diffusivities in the CMAS composition, we predict an increase in the normalized Cd/Re ratio in the gas phase with increasing bubble growth rate. Monitoring of the Cd/Re ratios in aerosols from degassing volcanoes may provide a tool for predicting volcanic eruption. (C) 2008 Elsevier B.V. All rights reserved.