Regiospecific side-chain functionalization of linear low-density polyethylene with polar groups

被引：82

作者：

Bae, CS

Hartwig, JF

Chung, HY

Harris, NK

Switek, KA

Hillmyer, MA

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

[2] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[3] Univ Nevada, Dept Chem, Las Vegas, NV 89154 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 39期

关键词：

boron; C-H activation; homogeneous catalysis; polymers; rhodium;

D O I：

10.1002/anie.200501837

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The tail end: The Rh-catalyzed selective functionalization of commercial linear low-density polyethylene (LLDPE) with boron reagents is demonstrated. Subsequent oxidation and transformations of the boron-containing polymer yields materials that contain a variety of polar functionalities, such as hydroxy, amino, and formyl groups, at the termini of the side chains (see scheme). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6410 / 6413

页数：4

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