Spectroscopic studies of neodymium and europium phosphoro-azo beta-diketonates

被引：35

作者：

Amirkhanov, V

Ovchinnikov, V

Legendziewicz, J

Graczyk, A

Hanuza, J

Macalik, L

机构：

[1] UNIV WROCLAW,FAC CHEM,PL-50383 WROCLAW,POLAND

[2] MIL TECH ACAD,INST CHEM,PL-01489 WARSAW,POLAND

[3] POLISH ACAD SCI,INST LOW TEMP & STRUCT RES,PL-50950 WROCLAW,POLAND

来源：

ACTA PHYSICA POLONICA A | 1996年 / 90卷 / 02期

关键词：

D O I：

10.12693/APhysPolA.90.455

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

New complexes of lanthanides (Nd, Eu) with phosphoro-azo derivatives of beta-diketones were synthesized. Optical properties of these compounds were investigated and confronted with the structure and single crystal spectra of different types of earlier reported lanthanide phosphoro-azo beta-diketonates. The exchange of the N-P-O-Me ligand group by the N-P-NR(2) one plays only a minor role in binding character of lanthanide ions but strongly affects biological functions and properties of lanthanide systems. In vitro experiment on cytotoxicity of the samples was performed using 10T(1/2), L(1), MCF, DETA and Me omega-132 cell lines.

引用

页码：455 / 460

页数：6