Spectroscopic studies of neodymium and europium phosphoro-azo beta-diketonates

被引:35
作者
Amirkhanov, V
Ovchinnikov, V
Legendziewicz, J
Graczyk, A
Hanuza, J
Macalik, L
机构
[1] UNIV WROCLAW,FAC CHEM,PL-50383 WROCLAW,POLAND
[2] MIL TECH ACAD,INST CHEM,PL-01489 WARSAW,POLAND
[3] POLISH ACAD SCI,INST LOW TEMP & STRUCT RES,PL-50950 WROCLAW,POLAND
关键词
D O I
10.12693/APhysPolA.90.455
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
New complexes of lanthanides (Nd, Eu) with phosphoro-azo derivatives of beta-diketones were synthesized. Optical properties of these compounds were investigated and confronted with the structure and single crystal spectra of different types of earlier reported lanthanide phosphoro-azo beta-diketonates. The exchange of the N-P-O-Me ligand group by the N-P-NR(2) one plays only a minor role in binding character of lanthanide ions but strongly affects biological functions and properties of lanthanide systems. In vitro experiment on cytotoxicity of the samples was performed using 10T(1/2), L(1), MCF, DETA and Me omega-132 cell lines.
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收藏
页码:455 / 460
页数:6
相关论文
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