Intercomparison of methods for sampling and analysis of atmospheric mercury species

被引:144
作者
Munthe, J
Wängberg, I
Pirrone, N
Iverfeldt, Å
Ferrara, R
Ebinghaus, R
Feng, X
Gårdfeldt, K
Keeler, G
Lanzillotta, E
Lindberg, SE
Lu, J
Mamane, Y
Prestbo, E
Schmolke, S
Schroeder, WH
Sommar, J
Sprovieri, F
Stevens, RK
Stratton, W
Tuncel, G
Urba, A
机构
[1] Swedish Environm Res Inst, IVL, S-40258 Gothenburg, Sweden
[2] Univ Calabria, CNR, Inst Atmospher Pollut, IIA, I-87036 Rende, Italy
[3] CNR, Inst Biophys, I-57127 Pisa, Italy
[4] GKSS Forschungszentrum Geesthacht GmbH, Inst Phys & Chem Anal, D-21502 Geesthacht, Germany
[5] Gothenburg Univ, Dept Chem, S-41296 Gothenburg, Sweden
[6] Univ Michigan, Air Qual Lab, Ann Arbor, MI 48109 USA
[7] Oak Ridge Natl Lab, Div Environm Sci, Oak Ridge, TN 37831 USA
[8] Environm Canada, Atmospher Environm Serv, Downsview, ON M3H 5T4, Canada
[9] Technion Israel Inst Technol, IL-32000 Haifa, Israel
[10] Frontier Geosci Ltd, Seattle, WA 98109 USA
[11] US EPA, FL Dept Environm Protect, Res Triangle Pk, NC 27711 USA
[12] Earlham Coll, Dept Chem, Richmond, IN 47374 USA
[13] Middle E Tech Univ, Dept Environm Engn, TR-06531 Ankara, Turkey
[14] Inst Phys, Environm Res Dept, LT-2600 Vilnius, Lithuania
关键词
mercury; measurement; atmosphere; speciation;
D O I
10.1016/S1352-2310(01)00104-2
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
An intercomparison for sampling and analysis of atmospheric mercury species was held in Tuscany, June 1998. Methods for sampling and analysis of total gaseous mercury (TGM), reactive gaseous mercury (RGM) and total particulate mercury (TPM) were used in parallel sampling over a period of 4 days. The results show that the different methods employed for TGM compared well whereas RGM and TPM showed a somewhat higher variability. Measurement results of RGM and TPM improved over the time period indicating that activities at the sampling site during set-up and initial sampling affected the results. Especially the TPM measurement results were affected. Additional parallel sampling was performed for two of the TPM methods under more controlled conditions which yielded more comparable results. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3007 / 3017
页数:11
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