A kinetic investigation of chromium

被引:15
作者
Kocaoba, S [1 ]
Akcin, G [1 ]
机构
[1] Yildiz Tech Univ, Fac Art & Sci, Dept Chem, Istanbul, Turkey
来源
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY | 2003年 / 9卷 / 02期
关键词
kinetics; chelating weakly acidic exchange resin; chromium; Kressman-Kitchener stirrer reactor;
D O I
10.1023/A:1024293310492
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A kinetic investigation was performed with an ion exchange resin for chromium. A chelating cation exchange resin ( Amberlite IRC 718) was used for removal and recovery of chromium. The effect of concentration, resin amount, particle size and stirring speed on kinetics were investigated. The metal concentration range studied was between 5 to 160 mg L-1, the resin amount range was between 5 to 20 mg, the particle size range was between 0.35 to 1.8 mm and the stirring speed range was between 1000 to 3500 rpm. Kinetic studies were done using a Kressman-Kitchener stirrer reactor system and the results were compared with existing kinetic models. Two models; Nernst-Plank film diffusion control model (fdc) and solid phase diffusion control model (pdc) were identified and the dependence of the rate on parameters, such as solution concentration, particle size, resin amount, stirring speed, etc., was examined for each of them. As a result, interpretation of these data showed that the system is probably controlled both film and particle diffusion.
引用
收藏
页码:143 / 151
页数:9
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