Protide compounds in hydrogen storage systems

被引：79

作者：

Li, ZP ^{[1
]}

Liu, BH ^{[1
]}

Arai, K ^{[1
]}

Morigazaki, N ^{[1
]}

Suda, S ^{[1
]}

机构：

[1] Kogakuin Univ, Dept Environm Chem & Engn, Hachioji, Tokyo 1920015, Japan

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2003年 / 356卷

关键词：

protide compound; NaBH4; saline hydride; hydrogen energy system; fuel cell; fuel recovery;

D O I：

10.1016/S0925-8388(02)01241-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Based on three chemical states of hydrogen: protide (H-), protium (H-o) and proton (H+), a triangular hydrogen energy system was proposed. The transfers among protide, protium and proton attracted our attention. We experimentally proved that NaBH4 as a protide carrier can release its energy through a fuel cell (borohydride fuel cell) directly or generate hydrogen gas for polymer electrolyte membrane fuel cell application. The used fuel (meta-borate) can be reverted to NaBH, through a reaction with a saline hydride (MgH2). (C) 2002 Elsevier B.V. All rights reserved.

引用

页码：469 / 474

页数：6

共 13 条

[1] AMEDOLA S, 1998, Patent No. 5804329
[2] DYMOVA TN, 1975, DOKL AKAD NAUK SSSR+, V224, P591
[3] GEORRIG D, 1958, Patent No. 1077644
[4] GOERRIG D, 1956, Patent No. 1036222
[5] SODIUM BOROHYDRIDE, AN INTERESTING ANODIC FUEL .1.
INDIG, ME
SNYDER, RN
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1962, 109 (11) : 1104 - 1106
[6] JASINSKI R, 1965, ELECTROCHEM TECHNOL, V3, P40
[7] Lee J.Y., 1997, US Patent, Patent No. 5599640
[8] OGG RA, 1955, DISCUSS FARADAY SOC, P239
[9] PECSOK RL, 1953, J AM CHEM SOC, V76, P2862
[10] NEW DEVELOPMENTS IN THE CHEMISTRY OF DIBORANE AND OF THE BOROHYDRIDES .9. SODIUM BOROHYDRIDE, ITS HYDROLYSIS AND ITS USE AS A REDUCING AGENT AND IN THE GENERATION OF HYDROGEN
SCHLESINGER, HI
BROWN, HC
FINHOLT, AE
GILBREATH, JR
HOEKSTRA, HR
HYDE, EK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (01) : 215 - 219

← 1 2 →