[{(Mo)Mo5O21(H2O)3(SO4)}12(VO)30(H2O)20]36-:: A molecular quantum spin icosidodecahedron

被引：89

作者：

Botar, B

Kögerler, P

Hill, CL

机构：

[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

[2] Iowa State Univ, Ames Lab, Ames, IA 50011 USA

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 25期

关键词：

D O I：

10.1039/b504491j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembly of aqueous solutions of molybdate and vanadate under reducing, mildly acidic conditions results in a polyoxomolybdate-based {Mo72V30} cluster compound Na8K16(VO)(H2O)(5)[K-10 subset of{(Mo)Mo5O21(H2O)(3)(SO4)}(12)(VO)(30)-(H2O)(20)]center dot 150H(2)O, 1, a quantum spin-based Keplerate structure.double dagger

引用

页码：3138 / 3140

页数：3

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