Polyoxometalates containing late transition and noble metal atoms

被引:184
作者
Putaj, Piotr [1 ]
Lefebvre, Frederic [1 ]
机构
[1] Univ Lyon 1, CPE Lyon, CNRS, UMR,C2P2,LCOMS, F-69616 Villeurbanne, France
关键词
Polyoxometalate; Noble metal; Structure; Catalysis; KEGGIN-TYPE POLYOXOTUNGSTATES; TRIPLE CUBANE-TYPE; N-HEXANE CRACKING; AMPHIPHILIC ORGANORUTHENIUM OXOMOLYBDENUM; ORGANOMETALLIC RUTHENIUM(II) COMPLEXES; DIRHODIUM-SUBSTITUTED POLYOXOMETALATE; ATOMICALLY DISPERSED IRIDIUM(I); ANCHORED HOMOGENEOUS CATALYSTS; DAWSON-TYPE POLYOXOTUNGSTATES; CHIRAL ALLYLIC ALCOHOLS;
D O I
10.1016/j.ccr.2011.01.030
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This review describes the state of the art in the field of polyoxometalates containing noble metal atoms (ruthenium, rhodium, palladium, silver, osmium, iridium, platinum and gold). The structures of the various species are listed together with their applications (mainly in catalysis). (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:1642 / 1685
页数:44
相关论文
共 327 条
[1]  
A Seddon KR Seddon E., 1984, The Chemistry of Ruthenium, P156
[2]   Controllable growth of chains and grids from polyoxomolybdate building blocks linked by silver(I) dimers [J].
Abbas, H ;
Pickering, AL ;
Long, DL ;
Kögerler, P ;
Cronin, L .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (04) :1071-1078
[3]   Molecular growth of polyoxometalate Architectures based on [-Ag{Mo8}Ag-] synthons:: Toward designed cluster assemblies [J].
Abbas, Hamera ;
Streb, Carsten ;
Pickering, Alexandra L. ;
Neil, Andrew R. ;
Long, De-Liang ;
Cronin, Leroy .
CRYSTAL GROWTH & DESIGN, 2008, 8 (02) :635-642
[4]   Crystallographic and dynamic NMR evidence for organometallic fragments pivoting on a molecular oxide surface [J].
Abe, M ;
Isobe, K ;
Kida, K ;
Yagasaki, A .
INORGANIC CHEMISTRY, 1996, 35 (18) :5114-5115
[5]  
ABE M, 1994, J CLUST SCI, V5, P565
[6]  
ABE M, 1996, J CLUST SCI, V7, P103
[7]   Chiral hydroperoxides as oxygen source in the catalytic stereoselective epoxidation of allylic alcohols by sandwich-type polyoxometalates:: Control of enantioselectivity through a metal-coordinated template [J].
Adam, W ;
Alsters, PL ;
Neumann, R ;
Saha-Möller, CR ;
Seebach, D ;
Beck, AK ;
Zhang, R .
JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (21) :8222-8231
[8]  
Adam W, 2002, SYNLETT, P2011
[9]   A highly chemoselective, diastereoselective, and regioselective epoxidation of chiral allylic alcohols with hydrogen peroxide, catalyzed by sandwich-type polyoxometalates:: Enhancement of reactivity and control of selectivity by the hydroxy group through metal-alcoholate bonding [J].
Adam, W ;
Alsters, PL ;
Neumann, R ;
Saha-Möller, CR ;
Sloboda-Rozner, D ;
Zhang, R .
JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (05) :1721-1728
[10]   Self-assembly of extended high-dimensional architectures from Anderson-type polyoxometalate clusters [J].
An, HY ;
Li, YG ;
Xiao, DR ;
Wang, EB ;
Sun, CY .
CRYSTAL GROWTH & DESIGN, 2006, 6 (05) :1107-1112