Trichloroisocyanuric acid: an efficient reagent for the synthesis of dialkyl chlorophosphates from dialkyl phosphites

被引:32
作者
Acharya, J [1 ]
Gupta, AK [1 ]
Shakya, PD [1 ]
Kaushik, MP [1 ]
机构
[1] Def Res & Dev Estab, Proc Technol Dev Div, Gwalior 474002, MP, India
关键词
dialkyl phosphite; dialkyl chlorophosphate; trichloroisocyanuric acid; cyanuric acid;
D O I
10.1016/j.tetlet.2005.06.024
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A mild and operationally simple method for the synthesis of dialkyl chlorophosphates is described. Trichloroisocyanuric acid is used as an effective reagent for the rapid conversion of dialkyl phosphites to their corresponding dialkyl chlorophosphates under mild conditions. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5293 / 5295
页数:3
相关论文
共 37 条
[1]   STUDIES ON PHOSPHORYLATION .4. FURTHER STUDIES ON THE USE OF DIBENZYL CHLOROPHOSPHONATE AND THE EXAMINATION OF CERTAIN ALTERNATIVE PHOSPHORYLATION METHODS [J].
ATHERTON, FR ;
HOWARD, HT ;
TODD, AR .
JOURNAL OF THE CHEMICAL SOCIETY, 1948, (AUG) :1106-1111
[2]  
ATHERTON FR, 1945, J ORG CHEM, V10, P660
[3]  
ATHERTON FR, 1945, J CHEM SOC, V36, P4237
[4]  
AUDRIETH LE, 1953, J ORG CHEM, V18, P1288
[5]  
CHAWALINSKI S, 1957, ROCZNIKI CHEM, V31, P539
[6]  
CORBRIDGE DEC, STUDIES INORGANIC CH, V10
[7]   GEOMETRY OF TRANSITION STATE IN HYDROLYSIS OF PHOSPHATE ESTERS [J].
DENNIS, EA ;
WESTHEIMER, FH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (14) :3432-+
[8]   The synthesis of vicinal halohydrin phosphates via highly regioselective ring opening of epoxides with dialkyl halophosphate [J].
Ding, YX ;
Hu, J .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2000, (10) :1651-1655
[9]   THE STRUCTURE OF PB-1, AN UNUSUAL TOXIN ISOLATED FROM THE RED TIDE DINOFLAGELLATE PTYCHODISCUS-BREVIS [J].
DINOVI, M ;
TRAINOR, DA ;
NAKANISHI, K ;
SANDUJA, R ;
ALAM, M .
TETRAHEDRON LETTERS, 1983, 24 (09) :855-858
[10]   PHOSPHONATES AS ANALOGS OF NATURAL PHOSPHATES [J].
ENGEL, R .
CHEMICAL REVIEWS, 1977, 77 (03) :349-367