Near-infrared Absorbing Squarylium Dyes with Linearly Extended π-Conjugated Structure for Dye-sensitized Solar Cell Applications

被引:66
作者
Maeda, Takeshi [1 ]
Hamamura, Yuuto [1 ]
Miyanaga, Kyohei [1 ]
Shima, Naoki [1 ]
Yagi, Shigeyuki [1 ]
Nakazumi, Hiroyuki [1 ]
机构
[1] Osaka Prefecture Univ, Dept Appl Chem, Grad Sch Engn, Naka Ku, Sakai, Osaka 5998531, Japan
关键词
UNSYMMETRICAL SQUARAINE DYES; NANOCRYSTALLINE TIO2 FILMS; EFFICIENT FAR-RED; MOLECULAR DESIGN; ORGANIC-DYES;
D O I
10.1021/ol2024345
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel class of near-infrared absorbing squarylium sensitizers with linearly extended pi-conjugated structures, which were obtained by Pd-catalyzed cross-coupling reactions with stannylcyclobutenediones, has been developed for dye-sensitized solar cells. The cells based on these dyes exhibited a significant spectral response in the near-Infrared region over 750 nm in addition to the visible region.
引用
收藏
页码:5994 / 5997
页数:4
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