Solid-state conversion of processable 3,4-ethylenedioxythioplhene (EDOT) containing poly(arylsilane) precursors to π-conjugated conducting polymers

被引：29

作者：

Bokria, Jayesh G.

Kumar, Arvind

Seshadri, Venkataramanan

Tran, Arlene

Sotzing, Gregory A. ^{[1
]}

机构：

[1] Univ Connecticut, Dept Chem, Storrs, CT 06269 USA

[2] Univ Connecticut, Inst Mat Sci, Polymer Program, Storrs, CT 06269 USA

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 06期

关键词：

D O I：

10.1002/adma.200602023

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of processable poly(arylsilane) precursor polymer, which is converted electrochemically into the conjugated polymer in the processed solid state, is reported. This used process can be used to make other conjugated polymers from precursors having different aromatic moieties.

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页码：1175 / +

页数：5

相关论文

共 28 条

[1] Oxidative polymerisation of silyl monomers.: Applications and limits [J].

Bouachrine, M ;

Lère-Porte, JP ;

Moreau, JJE ;

Sauvajol, JL ;

Serein-Spirau, F ;

Torreilles, C .

SYNTHETIC METALS, 1999, 101 (1-3) :15-16

[2] ROLE OF SILICON IN POLYMER SYNTHESIS - ACTIVATION OF THE OXIDATIVE COUPLING OF THIOPHENE BY TRIMETHYLSILYL SUBSTITUENTS - A ROUTE TO HIGH-MOLECULAR-WEIGHT POLY(3-ALKYL)THIOPHENE [J].

BOUACHRINE, M ;

LEREPORTE, JP ;

MOREAU, JJE ;

MAN, MWC .

JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (05) :797-799

[3] Syntheses and electropolymerization behavior of ethylenedioxythiophene-substituted silanes [J].

Chahma, M ;

Hicks, RG .

CANADIAN JOURNAL OF CHEMISTRY, 2004, 82 (11) :1629-1633

[4] THE 1ST REGIOREGULAR HEAD-TO-TAIL POLY(3-HEXYLTHIOPHENE-2,5-DIYL) AND A REGIORANDOM ISOPOLYMER - NI VS PD CATALYSIS OF 2(5)-BROMO-5(2)-(BROMOZINCIO)-3-HEXYLTHIOPHENE POLYMERIZATION [J].

CHEN, TA ;

RIEKE, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (25) :10087-10088

[5]

ELSENBAUMER RL, 1986, J CHEM SOC CHEM COMM, P1346

[6] A new low band gap dithienylene-fluorovinylene electrochromic polymer: an intriguing effect of silyl substitution on the polymerisation reaction [J].

Gallazzi, MC ;

Ridolfi, G ;

Albertin, L ;

Bertarelli, C ;

Camaioni, N ;

Casalbore-Miceli, G ;

Fichera, AM .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (08) :2202-2207

[7] POLY(ALKYLENEDIOXYTHIOPHENE)S - NEW, VERY STABLE CONDUCTING POLYMERS [J].

HEYWANG, G ;

JONAS, F .

ADVANCED MATERIALS, 1992, 4 (02) :116-118

[8] Rapid direct nanowriting of conductive polymer via electrochemical oxidative nanolithography [J].

Jang, SY ;

Marquez, M ;

Sotzing, GA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (31) :9476-9477

[9] Poly(thiophene)s prepared via electrochemical solid-state oxidative cross-linking. A comparative study [J].

Jang, SY ;

Sotzing, GA ;

Marquez, M .

MACROMOLECULES, 2004, 37 (12) :4351-4359

[10] Intrinsically conducting polymer networks of poly(thiophene) via solid-state oxidative cross-linking of a poly(norbornylene) containing terthiophene moieties [J].

Jang, SY ;

Sotzing, GA ;

Marquez, M .

MACROMOLECULES, 2002, 35 (19) :7293-7300