Single-crystal characterization of Co7(OH)6(H2O)3(C4H4O4)4•7H2O;: A new cobalt succinate identified through high-throughput synthesis

被引：29

作者：

Forster, PM

Burbank, AR

O' Sullivan, MC

Guillou, N

Livage, C

Férey, G

Stock, N

Cheetham, AK ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[2] Univ Versailles, UMR 8637, CNRS, Inst Lavoisier, F-78035 Versailles, France

[3] Univ Kiel, Inst Anorgan Chem, D-24118 Kiel, Germany

来源：

SOLID STATE SCIENCES | 2005年 / 7卷 / 12期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/j.solidstatesciences.2005.04.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new form of cobalt succinate has been discovered using high-throughput methods and its structure was solved by single crystal X-ray diffraction. Co7(C4H4O4)(4)(OH)(6)(H2O)(3)center dot 7H(2)O crystallizes in the monoclinic space group P2(1)/c with cell parameters: a = 7.888(2) angstrom, b = 19.082(6) angstrom, c = 23.630(7) angstrom, beta = 91.700(5)degrees, V = 3555(2) angstrom(3), R-1 = 0.0469. This complex structure, containing 55 crystal lographically distinct non-hydrogen atoms, is compared to the previously reported nickel phase, characterized using ab initio structure solution from synchrotron powder diffraction data. (c) 2005 Published by Elsevier SAS.

引用

页码：1549 / 1555

页数：7

共 28 条

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