Porous Single-Crystalline Palladium Nanoparticles with High Catalytic Activities

被引:206
作者
Wang, Feng [1 ,2 ]
Li, Chuanhao [3 ]
Sun, Ling-Dong [1 ]
Xu, Chun-Hu [1 ]
Wang, Jianfang [2 ]
Yu, Jimmy C. [3 ]
Yan, Chun-Hua [1 ]
机构
[1] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
[2] Chinese Univ Hong Kong, Dept Phys, Shatin, Hong Kong, Peoples R China
[3] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
基金
中国国家自然科学基金;
关键词
C?C coupling; crystal growth; mesoporous materials; nanoparticles; palladium; SHAPE-CONTROLLED SYNTHESIS; HIGH-INDEX FACETS; ELECTROCATALYTIC ACTIVITY; BIMETALLIC NANODENDRITES; PLATINUM NANOPARTICLES; METAL NANOCRYSTALS; MEDIATED SYNTHESIS; OXYGEN REDUCTION; ROOM-TEMPERATURE; SHELL;
D O I
10.1002/anie.201107376
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Palladium's pore cousin: A facile approach is described for the size-controlled preparation of porous single-crystalline Pd nanoparticles. These porous Pd nanoparticles exhibit size-independent catalytic activities for the Suzuki coupling and are more active than commercial Pd/C catalysts. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4872 / 4876
页数:5
相关论文
共 35 条
[1]  
[Anonymous], 2006, ANGEW CHEM, DOI DOI 10.1002/ANGE.200603068
[2]  
[Anonymous], 2008, ANGEW CHEMIE, DOI DOI 10.1002/ANGE.200802750
[3]   Platinum nanoparticle shape effects on benzene hydrogenation selectivity [J].
Bratlie, Kaitlin M. ;
Lee, Hyunjoo ;
Komvopoulos, Kyriakos ;
Yang, Peidong ;
Somorjai, Gabor A. .
NANO LETTERS, 2007, 7 (10) :3097-3101
[4]   Seed-Mediated Synthesis of Palladium Nanorods and Branched Nanocrystals and Their Use as Recyclable Suzuki Coupling Reaction Catalysts [J].
Chen, Yi-Hsiu ;
Hung, Hsiao-Hui ;
Huang, Michael H. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (25) :9114-9121
[5]   Hierarchical magnetite/silica nanoassemblies as magnetically recoverable catalyst-supports [J].
Ge, Jianping ;
Huynh, Tuan ;
Hu, Yongxing ;
Yin, Yadong .
NANO LETTERS, 2008, 8 (03) :931-934
[6]   Thermally stable Pt/mesoporous silica core-shell nanocatalysts for high-temperature reactions [J].
Joo, Sang Hoon ;
Park, Jeong Young ;
Tsung, Chia-Kuang ;
Yamada, Yusuke ;
Yang, Peidong ;
Somorjai, Gabor A. .
NATURE MATERIALS, 2009, 8 (02) :126-131
[7]   Structural evolution of gold nanorods during controlled secondary growth [J].
Keul, Heidrun A. ;
Moeller, Martin ;
Bockstaller, Michael R. .
LANGMUIR, 2007, 23 (20) :10307-10315
[8]   Fabrication of hollow palladium spheres and their successful application to the recyclable heterogeneous catalyst for Suzuki coupling reactions [J].
Kim, SW ;
Kim, M ;
Lee, WY ;
Hyeon, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (26) :7642-7643
[9]   Morphological control of catalytically active platinum nanocrystals [J].
Lee, Hyunjoo ;
Habas, Susan E. ;
Kweskin, Sasha ;
Butcher, Derek ;
Somorjai, Gabor A. ;
Yang, Peidong .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (46) :7824-7828
[10]  
Li C., 2009, Angewandte Chemie, V121, P7015