Hierarchical assembly of a novel luminescent silver coordination framework with 4-(4-pyridylthiomethyl)benzoic acid

被引：26

作者：

Han, L ^{[1
]}

Wang, RH ^{[1
]}

Yuan, DQ ^{[1
]}

Wu, BL ^{[1
]}

Lou, BY ^{[1
]}

Hong, MC ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2005年 / 737卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Ag(I) complex; coordination polymer; hierarchical assembly; luminescence;

D O I：

10.1016/j.molstruc.2004.10.037

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel Ag(I) coordination polymer, [Ag-2(mu-ptmb)(mu(3)-ptmb)] . 2H(2)O (1), (ptmb = 4-(4-pyridylthiomethyl)benzoate), has been synthesized through self-assembly of AgNO3 with Hptmb in CH3CN/H2O mixed solution and characterized by elemental analysis and IR spectra. X-ray diffraction analysis shows that it is a 1D tape-like structure consisting of two kinds of rectangles, which is further hierarchically assembled by Ag...S and S...S weak interactions to form 3D open framework. Luminescence study indicates the complex has an emissive maximum at 500 nm in the solid state at room temperature. (C) 2004 Published by Elsevier B.V.

引用

页码：55 / 59

页数：5

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