Copolymers of vinyl epoxides with carbon monoxide

被引：22

作者：

Lee, JT ^{[1
]}

Alper, H ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ctr Catalysis Res & Innovat, Ottawa, ON K1N 6N5, Canada

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 22期

关键词：

D O I：

10.1039/b006641i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly functionalized alternating polyketones which possess epoxide groups in the side chains are synthesized by cationic palladium(II) complex catalyzed copolymerization of vinyl epoxides (non-conjugated diene monoepoxides) with carbon monoxide. Catalytic amounts of formic acid and 1,4-naphthoquinone promote the copolymerization significantly without effecting the epoxide group, with [Pd(L)(MeCN)(2)](BF4)(2) (L = (R,R)-Me-DUPHOS) as the catalyst.

引用

页码：2189 / 2190

页数：2

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