Characterization of Ni/SiO2 and Ni/Li-SiO2 catalysts for methane dry reforming

被引：100

作者：

Pompeo, F

Nichio, NN

González, MG

Montes, M

机构：

[1] Natl Univ La Plata, Fac Ciencias Exactas, CONICET, CINDECA, RA-1900 La Plata, Argentina

[2] Natl Univ La Plata, Fac Ingn, RA-1900 La Plata, Argentina

[3] Univ Basque Country, Fac Ciencias Quim, Dept Quim Aplicada, Grp Ingn Quim, E-20018 Donostia San Sebastian, Spain

来源：

CATALYSIS TODAY | 2005年 / 107-08卷

关键词：

nickel catalysts; lithium addition; catalyst characterization; methane dry reforming;

D O I：

10.1016/j.cattod.2005.07.024

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

In this study, catalysts based on nickel (15 wt.%. Ni) supported on SiO2 and silica modified by Li addition (0.1 and 1 wt.%. Li) were characterized for their application in dry reforming with carbon dioxide. Catalysts were characterized by using hydrogen chemisorption, H-2-TPR, XRD, DRIFTS and dry reforming reaction tests. The effect of the Li loading on the catalyst structure, the catalytic activity, stability and the deactivation rate by carbon formation are reported. The Li addition on the SiO2 support increases noticeably the resistance to deactivation by carbon deposition. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：856 / 862

页数：7

共 30 条

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