Alternating perpendicular 1-D channels in the supramolecular structure of the copper(II) complex [Cu(pyterpy)2](PF6)2 • CH3OH • 0.5 CH2Cl2 (pyterpy=4′-(4′′′-pyridyl)-2,2':6′,2′′-terpyridine)

被引：26

作者：

López, JS

Kraus, W

Reck, G

Thünemann, A

Kurth, DG

机构：

[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany

[2] Bundesanstalt Mat Forsch & Prufung, D-12489 Berlin, Germany

[3] Natl Inst Mat Sci, Tsukuba, Ibaraki 3050044, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 03期

关键词：

4 '-(4 '''-pyridyl)-2,2 ': 6 ' 2 ''-terpyridine; copper complexes; crystal structure; pi-pi stacking; supramolecular chemistry;

D O I：

10.1016/j.inoche.2004.12.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 4'-(4"'-pyridyl)-2,2':6',2"-terpyridine (pyterpy) with copper(II) yields the novel mononuclear [Cu(pyter-py)(2)](PF6)(2) complex. The crystal structure shows that the Cu(II) center is coordinated by the terpyridine domains of both pyterpy molecules, while the pyridyl tails remain uncoordinated. Intermolecular pi-pi stacking interactions between the cations in the crystal result in the formation of alternating I-D linear channels which run in perpendicular directions. (C) 2005 Elsevier B.V. All rights reserved.

引用

页码：281 / 284

页数：4

共 14 条

[1] Red and blue luminescent metallo-supramolecular coordination polymers assembled through π-π interactions [J].