Gas storage in structure H hydrates

被引:265
作者
Khokhar, AA
Gudmundsson, JS
Sloan, ED [1 ]
机构
[1] Colorado Sch Mines, Ctr Hydrate Res, Golden, CO 80401 USA
[2] Norwegian Univ Sci & Technol, Dept Petr Engn & Appl Geophys, N-7034 Trondheim, Norway
关键词
enthalpy; gas storage; hydrate; promoter; solid-fluid equilibria; structure H;
D O I
10.1016/S0378-3812(98)00338-0
中图分类号
O414.1 [热力学];
学科分类号
摘要
Three aspects of the storage of methane in structure H hydrate were investigated: (1) four-phase (L-W-H-V-L-HC) pressure-temperature equilibrium data are reported for 1,3-dimethylcyclohexane, a new structure H hydrate former, (2) in comparison with other hydrate structures it was shown that methane storage in sH hydrate is an attractive alternative if the large cage of sH is occupied with a large guest while the small cages are occupied by methane, and (3) polyvinylpyrrolidone (PVP) was found to promote the amount of hydrate formation. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:383 / 392
页数:10
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