Chemical compatibility of the LaFeO3 base perovskites (La0.6Sr0.4)(z)Fe(0.8)M(0.2)O(3-delta) (z=1, 0.9; M=Cr, Mn, Co, Ni) with yttria stabilized zirconia

被引：102

作者：

Kindermann, L ^{[1
]}

Das, D ^{[1
]}

Nickel, H ^{[1
]}

机构：

[1] FORSCHUNGSZENTRUM JULICH, INST MAT ENERGY SYST, RES CTR, D-52425 JULICH, GERMANY

来源：

SOLID STATE IONICS | 1996年 / 89卷 / 3-4期

关键词：

solid oxide fuel cell; yttria stabilized zirconia; perovskite;

D O I：

10.1016/0167-2738(96)00366-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Physicochemical compatibilities of the series of LaFeO3 base perovskites La(0.6)Sr(0.4)Fe(0.8)M(0.2)O(3-delta) and (La0.6Sr0.4)(0.9)Fe(0.8)M(0.2)O(3-delta) (M=Cr, Mn, Co, Ni) with the solid electrolyte yttria stabilized (8 mol% Y2O3) cubic zirconia, 8YSZ, were investigated. Powder mixtures of the perovskites with 8YSZ were annealed at 1000 degrees C for time periods up to 1300 h. The quenched samples were analyzed by XRD and SEM/EDX for identifying the reaction products. The results provide a working hypothesis for the development of improved compositions of cathode materials in solid oxide fuel cells.

引用

页码：215 / 220

页数：6

共 10 条

[1]

Chen C. C., 1993, Proceedings of the Third International Symposium on Solid Oxide Fuel Cells, P598

[2] SOLID-STATE DECOMPOSITIONS - THE INTERPRETATION OF KINETIC AND MICROSCOPIC DATA AND THE FORMULATION OF A REACTION-MECHANISM [J].

GALWEY, AK .

THERMOCHIMICA ACTA, 1985, 96 (02) :259-273

[3]

GALWEY AK, 1967, CHEM SOLIDS, P163

[4]

GORDES P, 1994, P 1 EUR SOL OX FUEL, P567

[5]

KINDERMANN L, UNPUB

[6]

KINDERMANN L, 1995, SOLID OXIDE FUEL CEL, P985

[7]

MACHLIN ES, 1991, THERMODYNAMICS KINET, P190

[8]

TAI LW, 1993, 3RD P INT S SOL OX F, P241

[9] PEROVSKITE-TYPE OXIDES AS OXYGEN ELECTRODES FOR HIGH-TEMPERATURE OXIDE FUEL-CELLS [J].

YAMAMOTO, O ;

TAKEDA, Y ;

KANNO, R ;

NODA, M .

SOLID STATE IONICS, 1987, 22 (2-3) :241-246

[10]

YOKOKAWA H, 1989, DENKI KAGAKU, V57, P821

← 1 →