Stereoselective synthesis of α-C-D-gluco- and D-galactopyranosyl glycosides from an isoprenoid synthon

被引：5

作者：

Jégou, A ^{[1
]}

Pacheco, C ^{[1
]}

Veyrières, A ^{[1
]}

机构：

[1] Ecole Natl Super Chim Rennes, Lab Synth & Activat Biomol, CNRS, ESA 6052, F-35700 Rennes, France

来源：

TETRAHEDRON | 1998年 / 54卷 / 49期

关键词：

D O I：

10.1016/S0040-4020(98)00926-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Addition of the allylsilane Me3SiCH2C:CH2CH2CO2Me to D-gluco and D-galactopyranosyl derivatives gives in good yields alpha-C-glycopyranosides which are easily converted into glycosylated beta-keto esters, butenolide and dihydropyrone. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：14779 / 14790

页数：12

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