A hybridization model for the plasmon response of complex nanostructures

被引:3425
作者
Prodan, E
Radloff, C
Halas, NJ
Nordlander, P
机构
[1] Rice Univ, Dept Chem, Houston, TX 77251 USA
[2] Rice Univ, Dept Phys, Houston, TX 77251 USA
[3] Rice Univ, Dept Elect & Comp Engn, Houston, TX 77251 USA
[4] Rice Univ, Rice Quantum Inst, Houston, TX 77251 USA
关键词
D O I
10.1126/science.1089171
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
We present a simple and intuitive picture, an electromagnetic analog of molecular orbital theory, that describes the plasmon response of complex nanostructures of arbitrary shape. Our model can be understood as the interaction or "hybridization" of elementary plasmons supported by nanostructures of elementary geometries. As an example, the approach is applied to the important case of a four-layer concentric nanoshell, where the hybridization of the plasmons of the inner and outer nanoshells determines the resonant frequencies of the multilayer nanostructure.
引用
收藏
页码:419 / 422
页数:4
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