Magnetite-embedded cellulose fibers prepared from ionic liquid

被引:119
作者
Sun, Ning [1 ]
Swatloski, Richard P. [1 ]
Maxim, Mirela L. [1 ]
Rahman, Mustafizur [1 ]
Harland, Adam G. [2 ,3 ]
Haque, Anwarul [2 ,3 ]
Spear, Scott K. [4 ]
Daly, Daniel T. [4 ]
Rogers, Robin D. [1 ]
机构
[1] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA
[2] Univ Alabama, Ctr Green Mfg, Tuscaloosa, AL 35487 USA
[3] Univ Alabama, Tuscaloosa, AL 35487 USA
[4] Univ Alabama, Alabama Inst Mfg Excellence, Tuscaloosa, AL 35487 USA
关键词
D O I
10.1039/b713194a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A dry-jet wet spinning process for making magnetically active cellulose fibers has been developed using the ionic liquid (IL) 1-ethyl-3-methylimidazolium chloride ([C(2)mim] Cl). Cellulose from different sources with various degrees of polymerization (DP) was used for making fibers by first dissolving the cellulose in the IL, dispersing particles of magnetite in the solution, and then coagulating the fibers in a water bath under appropriate spinning conditions. The variation of fiber properties with cellulose source and concentration of magnetite is discussed. Fiber texture was found to be related to overall magnetite concentration, cellulose concentration, and molecular weight in the spinning solution. In general, it was found that increasing DP and/or cellulose concentration resulted in more robust fibers, and conversely the addition of magnetite particles weakened the overall mechanical properties.
引用
收藏
页码:283 / 290
页数:8
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