Miniemulsion copolymerization using water-insoluble comonomers as cosurfactants

被引：27

作者：

Reimers, J ^{[1
]}

Schork, FJ ^{[1
]}

机构：

[1] GEORGIA INST TECHNOL,SCH CHEM ENGN,ATLANTA,GA 30332

来源：

POLYMER REACTION ENGINEERING | 1996年 / 4卷 / 2-3期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1080/10543414.1996.10744471

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Water-insoluble comonomers were found to impart diffusional stability to the miniemulsion droplets. These droplets became the principal site of nucleation and copolymerization. The resulting copolymer composition tended to follow what was predicted by the copolymer equation, and was governed by the reactivity ratios. In contrast copolymer compositions obtained from macroemulsion copolymerizations tended to be more influenced by the relative water-solubility of the comonomer and mass transfer.

引用

页码：135 / 152

页数：18

共 9 条

[1] CONTINUOUS MINIEMULSION POLYMERIZATION - KINETIC INVESTIGATIONS [J].