From coordination polymer macrocrystals to nanometric individual chains

被引：67

作者：

Olea, D

Alexandre, SS

Amo-Ochoa, P

Guijarro, A

de Jesús, F

Soler, JM

de Pablo, PJ

Zamora, F

Gómez-Herrero, J

机构：

[1] Univ Autonoma Madrid, Dept Quim Inorgan, ES-28049 Madrid, Spain

[2] Univ Autonoma Madrid, Dept Fis Mat Condensada, ES-28049 Madrid, Spain

[3] Univ Alfonso X Sabio, Dept Tecnol Ind, ES-28691 Madrid, Spain

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 14期

关键词：

D O I：

10.1002/adma.200401687

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Isolated single chains of the coordination polymer [Cd(6-MCP)(2)(.)2H(2)O](n) (6-MCP = 6-mercaptopurinate) (see Figure and inside cover) have been prepared by ultrasonic dispersion, ultracentrifugation, and deposition on a treated mica surface, and their mechanical and electrical properties studied. The observed insulating behaviour of the chains has been confirmed using density functional theory calculations.

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页码：1761 / +

页数：6

相关论文

共 42 条

[1] M-DNA:: A complex between divalent metal ions and DNA which behaves as a molecular wire [J].

Aich, P ;

Labiuk, SL ;

Tari, LW ;

Delbaere, LJT ;

Roesler, WJ ;

Falk, KJ ;

Steer, RP ;

Lee, JS .

JOURNAL OF MOLECULAR BIOLOGY, 1999, 294 (02) :477-485

[2] Small polarons in dry DNA [J].

Alexandre, SS ;

Artacho, E ;

Soler, JM ;

Chacham, H .

PHYSICAL REVIEW LETTERS, 2003, 91 (10)

[3] G-quartet biomolecular nanowires [J].

Calzolari, A ;

Di Felice, R ;

Molinari, E ;

Garbesi, A .

APPLIED PHYSICS LETTERS, 2002, 80 (18) :3331-3333

[4] Electrontransfer through DNA and metal-containing DNA [J].

Carell, T ;

Behrens, C ;

Gierlich, J .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2003, 1 (13) :2221-2228

[5] ONE-DIMENSIONAL COORDINATION POLYMERS - APPLICATIONS TO MATERIAL SCIENCE [J].

CHEN, CT ;

SUSLICK, KS .

COORDINATION CHEMISTRY REVIEWS, 1993, 128 (1-2) :293-322

[6] Visualization of single-walled carbon nanotubes electrical networks by scanning force microspy [J].

de Pablo, PJ ;

Gómez-Navarro, C ;

Gil, A ;

Colchero, J ;

Martinez, MT ;

Benito, AM ;

Maser, WK ;

Gómez-Herrero, J ;

Baró, AM .

APPLIED PHYSICS LETTERS, 2001, 79 (18) :2979-2981

[7] Absence of dc-conductivity in λ-DNA [J].

de Pablo, PJ ;

Moreno-Herrero, F ;

Colchero, J ;

Gomez-Herrero, J ;

Herrero, P ;

Baró, AM ;

Ordejón, P ;

Soler, JM ;

Artacho, E .

PHYSICAL REVIEW LETTERS, 2000, 85 (23) :4992-4995

[8]

de Pablo PJ, 2000, ADV MATER, V12, P573, DOI 10.1002/(SICI)1521-4095(200004)12:8<573::AID-ADMA573>3.3.CO

[9]

2-V

[10] Carbon nanotubes as molecular quantum wires [J].

Dekker, C .

PHYSICS TODAY, 1999, 52 (05) :22-28

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