Palladium(O)-catalyzed substitution of allylic substrates in perfluorinated solvents

被引:53
作者
Kling, R
Sinou, D
Pozzi, G
Choplin, A
Quignard, F
Busch, S
Kainz, S
Koch, D
Leitner, W
机构
[1] Univ Lyon 1, CNRS, CPE Lyon, Lab Synth Asymetr, F-69622 Villeurbanne, France
[2] Ctr CNR Sintesi & Stereochim Speciali Sistemi Org, I-20133 Milan, Italy
[3] Inst Rech Catalyse, CNRS, F-69626 Villeurbanne, France
[4] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
关键词
allylic substitution; palladium(0); perfluorinated solvent; perfluorinated ligands; recycling;
D O I
10.1016/S0040-4039(98)02188-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Palladium(0)-catalyzed alkylation reactions of allylic substrates can be performed using the new concept of fluorous biphasic system, allowing a very easy recycling of the catalyst. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:9439 / 9442
页数:4
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