Position-controlled ZnO nanoflower arrays grown on glass substrates for electron emitter application

被引:65
作者
Kim, Yong-Jin [1 ]
Yoo, Jinkyoung [1 ]
Kwon, Byoung-Hwa [1 ]
Hong, Young Joon [1 ]
Lee, Chul-Ho [1 ]
Yi, Gyu-Chul [1 ]
机构
[1] POSTECH, Dept Mat Sci & Engn, Natl CRI Ctr Semicond Nanorods, Pohang 790784, Gyeongbuk, South Korea
关键词
D O I
10.1088/0957-4484/19/31/315202
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The electron emission of position- controlled grown ZnO nanoflowers was investigated for application in cold cathode electron emission devices. ZnO nanoflower arrays, composed of several nanoneedles with sharp tips, were grown selectively on a conducting glass substrate using a chemical solution deposition method. The morphology and position of the ZnO nanoflowers were controlled by preparing polymethylmethacrylate submicron patterns using electron- beam lithography. Without the patterns, in contrast, vertical ZnO nanoneedles were randomly grown on the substrates with high density. Several samples prepared at the same conditions exhibited almost the same nanoflower morphology and field emission characteristics. Comparison of the field emission characteristics of the ZnO nanoflower arrays and ZnO nanoneedles showed that the arrays had excellent electron emission characteristics, with a low turn- on electric field of 0.13 V mu m(-1) at 0.1 mu A cm(-2) and a high emission current density of 0.8 mA cm(-2) in an applied electric field of 9.0 V mu m(-1). Furthermore, light-emitting devices made using ZnO nanoflower arrays demonstrated strong light emission, and micropixels for display application were clearly displayed.
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页数:5
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共 21 条
[1]   Enhanced field emission of ZnO nanowires [J].
Banerjee, D ;
Jo, SH ;
Ren, ZF .
ADVANCED MATERIALS, 2004, 16 (22) :2028-+
[2]   Site-specific growth to control ZnO nanorods density and related field emission properties [J].
Chang, CC ;
Chang, CS .
SOLID STATE COMMUNICATIONS, 2005, 135 (11-12) :765-768
[3]   Low-temperature wafer-scale production of ZnO nanowire arrays [J].
Greene, LE ;
Law, M ;
Goldberger, J ;
Kim, F ;
Johnson, JC ;
Zhang, YF ;
Saykally, RJ ;
Yang, PD .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (26) :3031-3034
[4]   Position-controlled selective growth of ZnO nanorods on Si substrates using facet-controlled GaN micropatterns [J].
Hong, Young Joon ;
An, Sung Jin ;
Jung, Hye Seong ;
Lee, Chul-Ho ;
Yi, Gyu-Chul .
ADVANCED MATERIALS, 2007, 19 (24) :4416-+
[5]   Time-resolved and time-integrated photoluminescence in ZnO epilayers grown on Al2O3(0001) by metalorganic vapor phase epitaxy [J].
Jung, SW ;
Park, WI ;
Cheong, HD ;
Yi, GC ;
Jang, HM ;
Hong, S ;
Joo, T .
APPLIED PHYSICS LETTERS, 2002, 80 (11) :1924-1926
[6]   Controlled selective growth of ZnO nanorod and microrod arrays on Si substrates by a wet chemical method [J].
Kim, Yong-Jin ;
Lee, Chul-Ho ;
Hong, Young Joon ;
Yi, Gyu-Chul ;
Kim, Sung Soo ;
Cheong, Hyeonsik .
APPLIED PHYSICS LETTERS, 2006, 89 (16)
[7]   Control of ZnO nanorod array density by Zn supersaturation variation and effects on field emission [J].
Kumar, R. T. Rajendra ;
McGlynn, Enda ;
McLoughlin, Conor ;
Chakrabarti, Subhananda ;
Smith, Richard C. ;
Carey, J. David ;
Mosnier, J. P. ;
Henry, Martin O. .
NANOTECHNOLOGY, 2007, 18 (21)
[8]   Field emission from well-aligned zinc oxide nanowires grown at low temperature [J].
Lee, CJ ;
Lee, TJ ;
Lyu, SC ;
Zhang, Y ;
Ruh, H ;
Lee, HJ .
APPLIED PHYSICS LETTERS, 2002, 81 (19) :3648-3650
[9]   Bound exciton and donor-acceptor pair recombinations in ZnO [J].
Meyer, BK ;
Alves, H ;
Hofmann, DM ;
Kriegseis, W ;
Forster, D ;
Bertram, F ;
Christen, J ;
Hoffmann, A ;
Strassburg, M ;
Dworzak, M ;
Haboeck, U ;
Rodina, AV .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2004, 241 (02) :231-260
[10]   Enhanced field emission properties from well-aligned zinc oxide nanoneedles grown on the Au/Ti/n-Si substrate [J].
Park, Chan Jun ;
Choi, Duck-Kyun ;
Yoo, Jinkyoung ;
Yi, Gyu-Chul ;
Lee, Cheol Jin .
APPLIED PHYSICS LETTERS, 2007, 90 (08)