Catalytic C-F bond activation of nonactivated monofluoroarenes

被引：105

作者：

Young, RJ ^{[1
]}

Grushin, VV ^{[1
]}

机构：

[1] Dupont Co, Dept Cent Res & Dev, Expt Stn, Wilmington, DE 19880 USA

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 03期

关键词：

D O I：

10.1021/om980887w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Catalytic hydrogenolysis of the C-F bond in most unreactive monofluoroarenes readily occurs under mild conditions, in the presence of homogeneous and/or heterogeneous Rh catalysts generated from [(Cy3P)(2)-Rh(H)Cl-2], H-2, and aqueous alkali.

引用

页码：294 / 296

页数：3

共 25 条

[1] HOMOGENEOUS METAL-CATALYZED HYDROGENOLYSIS OF C-F BONDS
AIZENBERG, M
MILSTEIN, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (33) : 8674 - 8675
[2] CATALYTIC ACTIVATION OF CARBON-FLUORINE BONDS BY A SOLUBLE TRANSITION-METAL COMPLEX
AIZENBERG, M
MILSTEIN, D
[J]. SCIENCE, 1994, 265 (5170) : 359 - 361
[3] DIBENZO[A,E]CYCLOOCTATETRAENE IN A PROPOSED TEST FOR HETEROGENEITY IN CATALYSTS FORMED FROM SOLUBLE PLATINUM GROUP METAL-COMPLEXES
ANTON, DR
CRABTREE, RH
[J]. ORGANOMETALLICS, 1983, 2 (07) : 855 - 859
[4] Recent advances in C-F bond activation
Burdeniuc, J
Jedlicka, B
Crabtree, RH
[J]. CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (02): : 145 - 154
[5] Catalytic photodefluorination of perfluoroalkanes to perfluoroalkenes with a ferrocene photosensitizer
Burdeniuc, J
Crabtree, RH
[J]. ORGANOMETALLICS, 1998, 17 (08) : 1582 - 1586
[6] MGH2 AS A REDUCING AGENT IN THE PRESENCE OF TRANSITION-METAL HALIDES .1. REDUCTION OF ORGANIC HALIDES
CARFAGNA, C
MUSCO, A
PONTELLINI, R
TERZONI, G
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1989, 57 (01): : 23 - 28
[7] NICKEL-CATALYZED CARBONYLATION OF AROMATIC HALIDES AT ATMOSPHERIC-PRESSURE OF CARBON-MONOXIDE
CASSAR, L
FOA, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 51 (APR16) : 381 - 393
[8] COMPLEX REDUCING AGENTS (CRAS) - VERSATILE, NOVEL WAYS OF USING SODIUM HYDRIDE IN ORGANIC-SYNTHESIS
CAUBERE, P
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1983, 22 (08): : 599 - 613
[9] Clark J.H., 1996, AROMATIC FLUORINATIO
[10] Cox J.D., 1970, THERMOCHEMISTRY ORGA

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