Synthesis and structures of (dialkylamino)ethylcyclopentadienyl derivatives of zinc

被引：21

作者：

Darensbourg, DJ ^{[1
]}

Wildeson, JR ^{[1
]}

Yarbrough, JC ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 21期

关键词：

D O I：

10.1021/om010519j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Lithium salts of (dialkylamino)ethylcyclopentadienyl react with either ZnCl2 or Zn(OAc)(2) to afford dimeric derivatives containing bridging chlorides or acetates, respectively. X-ray structural determinations of three such derivatives show that the cyclopentadienyl ligands are bound to the zinc centers in an eta (1) fashion and via their amine groups, thereby leading to a stable six-membered metallacycle.

引用

页码：4413 / 4417

页数：5

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