Synthesis, structure, and reactivity of novel dithiolato(oxo)rhenium(V) complexes

被引：45

作者：

Jacob, J

Guzei, IA

Espenson, JH ^{[1
]}

机构：

[1] Iowa State Univ Sci & Technol, Ames Lab, Ames, IA 50011 USA

[2] Iowa State Univ Sci & Technol, Dept Chem, Ames, IA 50011 USA

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 06期

关键词：

D O I：

10.1021/ic981367w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of methyltrioxorhenium(VII), MTO, with the dithiol o-HSC6H4CH2SH results in a dimeric rhenium(V) chelate, [CH3Re(O)(S-2(L))](2), where S-2(L) is the diithiolate ligand present as a chelate. The dimer is monomerized upon reaction with triphenylphosphine, giving the intensely green CH3(Ph3P)Re(O)(S-2(L)). The dimer reverts to MTO upon treatment with certain oxygen donors XO, such as pyridine-NO and Ph3AsO.

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页码：1040 / +

页数：3

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