Synthesis of vitamin-B12 derivatives with an electropolymerizable side chain

被引：19

作者：

Otten, T

Darbre, T

Cosnier, S

Abrantes, L

Correia, J

Keese, R

机构：

[1] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland

[2] Univ Grenoble 1, Lab Electrochim Organ & Photochim Redox, CNRS, UMR 5630, F-38041 Grenoble, France

[3] Univ Lisbon, Fac Ciencias, Dept Quim & Bioquim, P-1700 Lisboa, Portugal

来源：

HELVETICA CHIMICA ACTA | 1998年 / 81卷 / 06期

关键词：

D O I：

10.1002/hlca.19980810525

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three new derivatives of vitamin B-12 with a pyrrole head group attached to the corrin ring have been prepared. Ligand-exchange reactions and reduction provided reactive Co-III and Co-II complexes. Their electrochemical properties and their potential for fixation at the surface of electrodes by electropolymerization were studied.

引用

页码：1117 / 1126

页数：10

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